Well there are now 3 PocketC / ex-PocketC members
Getting going with eVC is not too difficult. There are plenty of resources for VC6++ and the embedded tools are so similar (environment wise) that any good book for VC will get you going.
If you feel like buying a book then consider Douglas Boling's 'Programming Microsoft Windows CE' even though it's pre PocketPC.
As for the differences between PocketC & eVC it's bad enough coming from PocketC for CE so you need to learn about the Windows message system by studying some samples. The rest of it is just coding.
Ian